Even heat-adapted people cannot carry out normal outdoor activities past a wet-bulb temperature of 32 °C (90 °F), equivalent to a heat index of 55 °C (130 °F)². The human body can't tolerate wet bulb temperatures that cross 35°C¹.
In other words, humans can no longer live when the peak wet bulb temperature reaches 35c. The chart below is in Fahrenheit, but the black zone is clear. I particularly note the wicked combination of humidity and temperature. As I write, humidity is 87% in Vancouver. Dangerous heat would be at just 80 degrees F. That's what we called a "heat dome" recently.